正偏心正交车铣精加工切削层几何形状研究

针对未考虑正偏心正交车铣切削层几何形状而导致难以全面反映正交车铣切削层几何形状变化规律的问题，基于正交车铣运动规律，在不考虑动力学影响的情况下，对切削层的形成过程进行了静态分析。建立的正偏心正交车铣切削层几何形状的解析模型涉及铣刀侧刃和底刃的切入/切出角度、切削厚度和切削深度。通过试验验证了该解析模型的正确性，并分析了切削参数对铣刀切削层的影响。研究结果为正偏心正交车铣切削层几何形状的变化提供了定量的分析依据，为切削力和颤振的研究提供了理论指导。     

Thermal management and catalytic combustion stability characteristics of premixed methane/air in heat recirculation meso‐combustors

In order to illuminate heat recirculation effect on catalytic combustion stability and further improve energy conversion efficiency in meso‐combustor, the catalytic combustion characteristics of the combustor with/without preheating channels are numerically studied at steady conditions. It is found that methane conversion rate and combustion efficiency increases by 2% to 3% and approximately 9% in the heat recirculation meso‐combustor, indicating that heat recirculation effect facilitates more complete combustion of methane and medium components. Preheating channels show positive effects on improving combustion stability in the heat recirculation meso‐combustor. On one hand, preheating channels facilitate heat recirculation effect, and heat recirculation rate exceeds 10% for all cases and reaches 31.8% with an inlet velocity of 0.5 m/s, leading to significant increment of methane‐specific enthalpy at the preheating channel outlet. On the other hand, Rh(s)/O(s) ratios of catalytic surface and catalytic surface temperature in main reaction zone are enlarged by the preheating channels, facilitating methane adsorption at catalytic surface. Specially, most of fuels are consumed in a shorter distance with higher methane conversion speed, which brings benefits to promote combustion efficiency and may be helpful to inhibit the combustion instability in heat recirculation meso‐combustors.     

高瓦斯矿井回采工作面瓦斯综合抽采技术实践

为了解决高瓦斯矿井工作面瓦斯涌出量大、瓦斯浓度高,制约工作面安全生产的问题,以亨元煤业为背景,结合矿井开采及瓦斯地质条件,确定了本煤层顺层钻孔抽采、穿层钻孔抽采邻近层和覆岩裂隙带瓦斯、以及对上隅角布置抽采管路进行抽采的综合治理方法。试验表明,工作面开采期间瓦斯涌出正常,上隅角瓦斯浓度保持在0.56%以下,实现了工作面安全高效开采。     

Reactivity,Selectivity, and Stability of Zeolite-Based Catalysts for Methane Dehydroaromatization

Non-oxidative dehydroaromatization is arguably the most promising process for the direct upgrading of cheap and abundant methane to liquid hydrocarbons. This reaction has not been commercialized yet because of the suboptimal activity and swift deactivation of benchmark Mo-zeolite catalysts. This progress report represents an elaboration on the recent developments in understanding of zeolite-based catalytic materials for high-temperature non-oxidative dehydroaromatization of methane. It is specifically focused on recent studies, relevant to the materials chemistry and elucidating i) the structure of active species in working catalysts; ii) the complex molecular pathways underlying the mechanism of selective conversion of methane to benzene; iii) structure, evolution and role of coke species; and iv) process intensification strategies to improve the deactivation resistance and overall performance of the catalysts. Finally, unsolved challenges in this field of research are outlined and an outlook is provided on promising directions toward improving the activity, stability, and selectivity of methane dehydroaromatization catalysts.     

Impacts of layout,surface condition and alloying elements on diffusion welding of micro process devices

The formation of a monolithic part during diffusion bonding is accompanied by the diffusion of atoms across the bonding planes. At sufficient low roughness, it mainly depends on the temperature and dwell time. At the same time, the diffusion process competes against grain growth. By adjusting an appropriate level of bearing pressure, it is possible to control deformation taking into account additional parameters resulting from mechanical microstructures and the design and aspect ratio of the part. Furthermore, material properties, such as the content of alloying elements, the degree of cold work hardening and the grain size, have an impact on diffusion and deformation behavior. Also the surface condition of mating surfaces is important to diffusion kinetics and the quality of the joint. Especially passivation layers of corrosion‐resistant alloys, such as stainless steels and nickel‐based alloys, impair diffusion. In contrast to this, cold work hardening at low depth below the surface, e. g. by means of a blasting processes, may facilitate formation of a good bond and help to limit grain size. For oxide dispersion‐strengthened materials, additional impacts on diffusion bonding behavior applies.     

Poly(L-lysine)-poly(ethylene glycol) layers with different structure and their influence on silica suspension stability

The effects of the structure of di- and triblock copolymers of poly(L-lysine) – LYS with poly(ethylene glycol) – PEG as well as the length of nonionic fragment in the LYS-PEG macromolecule on the copolymer chains conformation in the adsorption layer formed on the colloidal silica (SiO2) surface were examined. Spectrophotometry and turbidimetry were applied for the determination of copolymer adsorbed amounts and stability coefficients of silica aqueous suspensions. The electrokinetic parameters such as solid surface charge density and zeta potential were also estimated. The adsorption of LYS-PEG was proved to be the highest at pH 10 whereas the lowest adsorption on the solid surface was found for the triblock copolymer with long fragments of LYS at the same pH value.     

Indoor boundary layer chemistry modeling

Ozone (O₃) chemistry is thought to dominate the oxidation of indoor surfaces. We consider the hypothesis that reactions taking place within indoor boundary layers result in greater than anticipated hydroxyl radical (OH) deposition rates. We develop models that account for boundary layer mass‐transfer phenomena, O₃‐terpene chemistry and OH formation, removal, and deposition; we solve these analytically and by applying numerical methods. For an O₃‐limonene system, we find that OH flux to a surface with an O₃ reaction probability of 10^?8 is 4.3 × 10^?5 molec/(cm² s) which is about 10 times greater than predicted by a traditional boundary layer theory. At very low air exchange rates the OH surface flux can be as much as 10% of that for O₃. This effect becomes less pronounced for more O₃‐reactive surfaces. Turbulence intensity does not strongly influence the OH concentration gradient except for surfaces with an O₃ reaction probability >10^?4. Although the O₃ flux dominates OH flux under most conditions, OH flux can be responsible for as much as 10% of total oxidant uptake to otherwise low‐reactivity surfaces. Further, OH chemistry differs from that for ozone; therefore, its deposition is important in understanding the chemical evolution of some indoor surfaces and surface films.     

正电子湮没研究Al、Nb共掺CaCu3Ti4O12陶瓷高介电常数机理

关于CaCu₃Ti₄O₁₂陶瓷的高介电常数机理，目前广泛接受的是非本征的内阻挡层电容模型。该模型认为在多晶中元素变价、缺陷和非化学计量比等导致的半导化晶粒被绝缘晶界层，即内阻挡层所包围。其中内阻挡层的厚度对材料的介电性能影响较大，而扫描电子显微镜（SEM）测试表明样品晶界呈稀烂的果酱状，SEM难以测量晶界区域绝缘内阻挡层厚度。本文采用正电子湮没技术表征其厚度，通过对CaCu₃Ti₄O₁₂陶瓷共掺不同浓度的Al、Nb（CaCu₃Ti_4-xAl_0.5xNb_0.5xO₁₂，x=0.2%、0.5%、5.0%）改变其晶粒和晶界的微观结构，研究CaCu₃Ti₄O₁₂陶瓷高介电常数机理。正电子湮没结果显示，掺杂样品符合多普勒展宽谱S参数的变化趋势与平均寿命的变化趋势一致。x=0.5%掺杂样品的介电常数最高，其平均寿命、S参数和湮没长寿命成分均最小，阻挡层最薄。实验结果验证了描述CaCu₃Ti₄O₁₂陶瓷高介电常数机理的内阻挡层电容模型的预测。     

Evolution of properties of parts during MIM and sintering of recycled oxide particles

Metal injection moulding (MIM) is an established process for high volume production of complex shaped metallic parts using commercially available feedstocks. The characteristics of parts after moulding, debinding, and sintering cannot be simply predictable from raw materials because the properties get altered with the process parameters and the corresponding levels of porosity during processing steps. In this study, physical properties, microstructure, and mechanical properties of the MIM parts have been characterised to understand the evolution of strength during various steps in MIM processing. Feedstocks with different binder loading show a considerable difference in physical as well as mechanical characteristics. During sintering of parts which have solid loading of grinding sludge, simultaneous in situ reduction and densification takes place, whereas only densification occurs in carbonyl iron parts. It is, therefore, possible to make complex shaped parts of different levels of porosity from downgraded shop floor metallic waste.     

LaCr0.7Fe0.3O3-NiMn2O4 supported NTC composite ceramics with a sandwich-like structure

A novel sandwich-like structure was first proposed to adjust the electrical properties of NTC thermistors. The LaCr_0.7Fe_0.3O₃-NiMn₂O₄ supported composite ceramics with sandwich-like structure were initially fabricated via traditional solid-state reaction and uniaxial pressing methods, which allowed for the advantages of each component to be integrated into one material. X-Ray diffraction analysis indicates the ceramics mainly consisting of orthorhombic perovskite LaCr_0.7Fe_0.3O₃ and cubic spinel NiMn₂O₄ phases. SEM images manifest that the three layers adhered well to each other and exhibited high density. For electrical properties, the ρ_25°C was expanded to a wide range of 1182–110,233 Ω?cm and could be adjusted to the desired values by tuning the volume ratio of two basic layers, the B value was enhanced from 3358 K to 4167 K by NiMn₂O₄, and the thermal stability was improved by LaCr_0.7Fe_0.3O₃ with a resistance shift less than 0.55 % after annealing at 150 °C for 1500 h.